Question

Ok I had a quick question. How does Boiling point play a role in structures like propane, propene, propyne? If I were to see these molecules with the understanding that they are all non polar because

they just have C and H how could I tell which one has the highest/lowest boiling point really fast by just looking at the formula or the structure? Also my last question is how can you tell which element on the periodic table has the greatest polarizability?