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One of the staggered conformations of 2-methylbutane in Problem 3.21b is more stable than the other. Which one is more stable? Why? 

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Sight down the C-2—C-3 bond, and draw Newman projection formulas for the 

(c) Two most stable conformations of 2,3-dimethylbutane 

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Sight down the C-2—C-3 bond, and draw Newman projection formulas for the 

(b) Two most stable conformations of 2-methylbutane

 

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Sight down the C-2—C-3 bond, and draw Newman projection formulas for the 

(a) Most stable conformation of 2,2-dimethylbutane

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Give the IUPAC names of each of the following alkanes. 

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Give the IUPAC names of each of the following alkanes. 

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Give the IUPAC names of each of the following alkanes. 

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Match the following alkenes with the appropriate heats of hydrogenation:

Heats of hydrogenation in kJ/mol (kcal/mol): 151(36.2); 122(29.3); 114(27.3); 111(26.5); 105(25.1). 

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Write the structure of the major organic product formed in the reaction of 1-methylcyclohexene with each of the following:

(k) Product of part (j) treated with zinc and water 

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Write the structure of the major organic product formed in the reaction of 1-methylcyclohexene with each of the following:

(i) Peroxyacetic acid 

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Write the structure of the major organic product formed in the reaction of 1-methylcyclohexene with each of the following:

(h) Bromine in water 

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Write the structure of the major organic product formed in the reaction of 1-methylcyclohexene with each of the following:

(g) Bromine in carbon tetrachloride 

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Write the structure of the major organic product formed in the reaction of 1-methylcyclohexene with each of the following:

(f) Diborane in diglyme, followed by basic hydrogen peroxide

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Write the structure of the major organic product formed in the reaction of 1-methylcyclohexene with each of the following:

(e) Dilute sulfuric acid

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Write the structure of the major organic product formed in the reaction of 1-methylcyclohexene with each of the following:

(c) Hydrogen bromide in the presence of peroxides 

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Write the structure of the major organic product formed in the reaction of 1-methylcyclohexene with each of the following:

(a) Hydrogen chloride

 

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Write the structure of the major organic product formed in the reaction of 2-methyl-2-butene with each of the following:

(k) Product of part (j) treated with zinc and water 

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Write the structure of the major organic product formed in the reaction of 2-methyl-2-butene with each of the following:

(j) Ozone

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Write the structure of the major organic product formed in the reaction of 2-methyl-2-butene with each of the following:

(i) Peroxyacetic acid 

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Write the structure of the major organic product formed in the reaction of 2-methyl-2-butene with each of the following:

(h) Bromine in water 

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Write the structure of the major organic product formed in the reaction of 2-methyl-2-butene with each of the following:

(g) Bromine in carbon tetrachloride 

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Write the structure of the major organic product formed in the reaction of 2-methyl-2-butene with each of the following:

(f) Diborane in diglyme, followed by basic hydrogen peroxide

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Write the structure of the major organic product formed in the reaction of 2-methyl-2-butene with each of the following:

(e) Dilute sulfuric acid 

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Write the structure of the major organic product formed in the reaction of 2-methyl-2-butene with each of the following:

(c) Hydrogen bromide in the presence of peroxides

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Write the structure of the major organic product formed in the reaction of 2-methyl-2-butene with each of the following:

(a) Hydrogen chloride

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