Ch. 23 - AminesSee all chapters
All Chapters
Ch. 1 - A Review of General Chemistry
Ch. 2 - Molecular Representations
Ch. 3 - Acids and Bases
Ch. 4 - Alkanes and Cycloalkanes
Ch. 5 - Chirality
Ch. 6 - Thermodynamics and Kinetics
Ch. 7 - Substitution Reactions
Ch. 8 - Elimination Reactions
Ch. 9 - Alkenes and Alkynes
Ch. 10 - Addition Reactions
Ch. 11 - Radical Reactions
Ch. 12 - Alcohols, Ethers, Epoxides and Thiols
Ch. 13 - Alcohols and Carbonyl Compounds
Ch. 14 - Synthetic Techniques
Ch. 15 - Analytical Techniques: IR, NMR, Mass Spect
Ch. 16 - Conjugated Systems
Ch. 17 - Aromaticity
Ch. 18 - Reactions of Aromatics: EAS and Beyond
Ch. 19 - Aldehydes and Ketones: Nucleophilic Addition
Ch. 20 - Carboxylic Acid Derivatives: NAS
Ch. 21 - Enolate Chemistry: Reactions at the Alpha-Carbon
Ch. 22 - Condensation Chemistry
Ch. 23 - Amines
Ch. 24 - Carbohydrates
Ch. 25 - Phenols
Ch. 26 - Amino Acids, Peptides, and Proteins

Concept #1: Reductive Amination

Example #1: Provide the Major Product

Additional Problems
Provide the reagents to transform cycloheptanone to N-methylcycloheptanamine.   
Complete the following reaction by drawing the structure of the principal organic product in the box. Draw the correct stereochemistry in the product where necessary. Be sure the product possesses the correct number of carbons and other atoms.
What is the result of treating acetone with isopropylamine and NaBH 3CN? a) Isopropylamine b) Diisopropylamine c) Triisopropylamine d) (CH3)2C=N-CH(CH3)2 e) None of the above
Predict the major product(s) for the reaction below.  
Give the structure of the major product:
Predict the product of the following reaction.
For each of the following reactions, provide the missing starting material, reagent, or major product in the box provided.
Predict the product(s) below:
Provide the product for the following reaction:
Provide reagent to complete the following chemical transformation.
Provide reagent to complete the following chemical transformation.
Provide the major product for the following transformation.
Provide the major product for the following transformation.
Provide the major product for the following transformation.
Which of the following amines could not be prepared directly via reductive amination? 
Which of the following amines could not be prepared directly via reductive amination involving the reactions of an aldehyde or ketone with an amine? To solve this question, provide the carbonyl and amine for each amination reaction.
Propose a synthesis of the following amine via a reductive amination starting from any amine and carbonyl.
Propose a synthesis of the following amine via a reductive amination starting from any amine of 7 carbons or less and any ketone or aldehyde of 7 carbons or less.
Complete the following reaction by drawing the structure of the principal organic product in the box. Draw the correct stereochemistry in the product where necessary. Be sure your product possesses the correct number of carbons and other atoms.
Provide the major organic product(s) of the reaction below.  
Draw the product of the following reaction. 
For the reaction below: Draw the organic product.
Draw the product of the following reductive amination reaction.
Draw the product of the following reaction.
Complete the following equation.  
Predict the product(s) for the following reaction.a. Ib. IIc. IIId. IV