Standard Temperature and Pressure

In order to accurately study the effect that changes in pressure, temperature and moles have on volume, chemists will often run their experiments under Standard State conditions

Standard Temperature & Pressure

Concept: Understanding Standard State Conditions

1m
Video Transcript

Welcome back, guys! In this new video, we're going to take a look to see what happens to our gas behavior under standard states. We're going to say sometimes chemists want to understand the influences that pressure, volume or temperature have on a particular gas particle. To do this, they do these experiments under what we call standard conditions.
We're going to say that these standard conditions are sometimes referred to as STP. STP just means standard temperature and pressure. We're going to say standard temperature is zero degrees Celsius. which really is 273.15 Kelvin. Standard pressure is one atmosphere.

Concept: Standard Molar Volume

2m
Video Transcript

We're going to say under standard state conditions, the volume of one mole of any gas, an ideal gas just means a gas that behaves as though it's by itself. One mole of any gas under STP will then have the same volume. At STP, one mole of carbon dioxide, one mole of nitrogen gas, or one mole of helium gas – all of these gases look different. Some of them are just atoms by themselves. Others are different elements connected together.
Under standard state conditions, under STP, all moles of gases have the same volume. They all have 22.4 liters. We're going to say that this volume is known as our standard molar volume. Remember, under STP conditions, one mole of any type of gas will have that as their volume.

At STP, 1 mole of any ideal gas will occupy exactly 22.4 Liters of volume inside a container. 

Knowing the meaning of STP allows you to now further manipulate the Ideal Gas Law. 

Concept: Combined Gas Law

6m
Video Transcript

Let's look at this example which uses our STP concept. We're going to see a sample of Freon-12 occupies 20.7 liters at 25 degrees Celsius and 947 torrs. Now they're saying what is the volume under standard conditions. Remember, what are they asking me? They're asking me to find the volume. But here they already gave me a volume. This must be my volume 1 and this must be my volume 2. They also gave me a temperature and they gave me a pressure. Here, they’re saying under standard conditions. Standard condition means we have a standard pressure and a standard temperature.
Our P2 would be one 1 atmosphere and our standard temperature would be to 273.15 Kelvin. Since we’re deal with a gas, we write PV equals nRT. Again guys, we're dealing with two sets of data. Remember, what have we done when we have two sets of something, two volumes or two pressures? We’d have to check to see who they're talking about. They're talking about pressure, they’re talking about volume and they're talking about temperature. They're not talking about moles because moles are being held constant, so we ignore it. R is our constant as well so we ignore that too. Everything is not on the same side of the equation sign. Divide everything by T to bring it over to the left. PV over T, since we’re dealing with two sets of data, it’s P1V1 over T1 equals P2V2 over T2.
This creates a whole new type of gas law, which we call the combined gas law. We haven't seen that until now. This is our combined gas law P1V1 over T1 equals P2V2 over T2. This is our combined gas law. We're going to plug in the units that we know into this combined gas law. But first, you have to change the temperature into Kelvin and you have to change those 947 torrs into atmospheres. T1 is 25 degrees Celsius, so all we have to do is add 273.15 which gives us 298.15 Kelvin. Pressure 1 is 947 torrs. We just have to change this to atmospheres. For every 1 atmosphere it's 760 torrs. When we do that, we get our answer as 1.24605 atmospheres. All we have to do now is plug it in and solve for our missing variable. Our P1 is 1.24605 atmospheres. Our volume 1 I told you was 20.7 liters. Our temperature 1 was 298.15
Kelvin, equals.
The pressure 2 was 1 atmosphere. That's really not going to change anything, so we plug it in anyways, 1 atmospheres. V2 is what we're looking for over temperature 2 which is 273.15 Kelvin. What we're going to do here is we’re just going to solve for everything on the left. Do the P1 times the V1 divided by T1. When we do all of that, the left side gives me 0.086511 liters times atmospheres over K. This still equals my 1 atmosphere times V2 divided by 273.15 Kelvin. Multiply both sides now by the 273.15 Kelvin. Kelvins cancel out, so then that’s going to give me 23.6305 liters times atmospheres still equals 1 atmosphere times V2. Divide both sides by the 1 atmosphere, which doesn't do anything. All it does is it helps get rid of these atmospheres in the units. So then V2 equals, we're going to just do 3 sig figs here. It's 23.6 liters. That would be the answer for our volume 2.
Again guys, remember even though we started out with the ideal gas law, because we have two sets of data again, we have to manipulate the ideal gas law. Doing that helped us isolate our answer here for V2. Now that you’ve seen this and now that you understand what STP is, I want you guys to attempt the next question.

Problem: What volume will 5.72 x 1025 atoms of argon gas occupy at STP?

4m

Gas Law Applications

Concept: Using the Ideal Gas Law to find density or molar mass

2m
Video Transcript

We're going to say that we're used to seeing the ideal gas law as PV equals nRT. But we should realize that we can manipulate this equation further in order to find the molar mass of the gas, or the density of a gas. Here, to find the molar mass of a gas, we change it. This capital M is not molarity, it's molar mass. Remember, the units for molar mass or molecular mass are grams per mole. We’re going to say the molar mass of a gas is equal to mRT over PV. We're going to say m represents the mass of the gas in grams, and then all the other variables stay the same. R is still our gas constant. Temperature is still in Kelvin. P is still in atmospheres and volume is still in liters.
If we want to find the density of a gas, we could say the density of a gas is equal to pressure times the molar mass divided by RT. This can become our equation. We could also further manipulate if we wanted the second equation. We could have combined mass and volume together to give us one thing. Remember, mass over volume helps us find density. We could have manipulated this further by saying molar mass of a gas is equal to density times RT over P. We could have used this as well. But then again, if we have a question dealing with the density of a gas, we know we could use this one and we could just manipulate it.
Even though this is a potential equation, we can get to it by just manipulating this third one. I’d recommend just remembering these three. If you're dealing with a question that gives you density and wants the molecular weight, you just use the third one. Manipulate it to find your answer.

The Ideal Gas Law can be further manipulated into new equations. These new equations can help us find the density or molar mass of a gas. 

When calculating the density of a gas it is essentially to also recall the formula of that gas in order to find the molar mass, M. 

Problem: What is the density of chlorine gas at STP?

3m

Remember that units for molar mass are grams of compound divided by the moles of that compound. 

Problem: An unknown gas sample weighs 3.12 g. If it has a volume of 0.206 µL when the temperature is 45oC and the pressure is 957 torr. What is its molar mass?

4m

Standard Temperature and Pressure Additional Practice Problems

A sample of carbon dioxide gas (CO2) has a volume of 2.5 L at standard temperature and pressure (STP). 

How many molecules of carbon dioxide gas are in the sample? 

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If the density of an ideal gas at STP if found to be 0.716 g/L, what is its molar mass? 

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Be sure to answer in the provided box.

How many moles of gaseous arsine (AsH3) occupy 0.273 L at STP? 

What is the density of gaseous arsine? 

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Enter your answer in the provided box.

A sample of Freon-12(CF2Cl2) occupies 10.0 L at 293 K and 128.00 kPa. Find its volume at STP. 

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A sample of oxygen gas has a volume of 2.50 L at STP. How many grams of O2 are present? 

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An open flask sitting in a lab fridge looks empty, but we know that actually it is filled with a mixture of gases called air. If the flask volume is 1.50L, and the air is at standard temperature and pressure, how many gaseous molecules does the flask contain?

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Calculate the volume occupied by 56.5 g of argon gas at STP. 

22.4 L 31.7 L 34.6 L 1, 270 L 1, 380 L


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Calculate the volume of 63.5 g of carbon monoxide at STP Report your answer to one decimal place!

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A gas at 772 mmHg and 35.0°C occupies a volume of 6.85 L. Calculate its volume at STP.

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Calculate its volume (in liters) of 88.4 g of CO2 at STP.

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The temperature of 2.5 L of a gas initially at STP is raised to 250°C at constant volume. Calculate the final pressure of the gas in atm.

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What is the significance of STP in relation to the volume of 1 mole of an ideal gas?

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Which of the following samples will have the greatest volume at STP?

a. 22 g Ne

b. 22 g He

c. 22 g O2

d. 22 g Cl

e. All have the same V at STP

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When aluminum is placed in concentrated hydrochloric acid, hydrogen gas is produced.

What volume of H2(g) is produced when 6.2g of Al(s) reacts at STP?

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One mole of nitrogen and one mole of neon are combined in a closed container at STP.

How big is the container?

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Consider three 1-L flasks at STP. Flask A contains NH 3  gas, flask B contains NO2  gas, and flask C contains N2  gas. In which flask are the molecules least polar and therefore most ideal in behavior?

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Methane, CH4(g), reacts with steam to give synthesis gas, a mixture of carbon monoxide and hydrogen.

CH4 (g) + H2O(g) → CO(g) + H2(g) [unbalanced]

What mass of hydrogen is formed if 275 L of methane (measured at STP) is converted to synthesis gas?

 

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Consider the following gas phase reaction:
2NO(g) + O2(g) → 2NO2(g)
400. mL of NO at STP is reacted with 500. mL of O2 at STP. Calculate the volume of the reaction mixture at STP after thev reaction goes to completion.

a. 700 mL

b. 800 mL

c. 900 mL

d. 1300 mL

e. 100 mL

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What volume will 0.780 moles of Xe occupy at STP?

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A sample of helium (He) occupies 4 liters at STP. What pressure is necessary to change the volume to 2 liters at 20°C?

1. 2.1464 atm

2. 2.0 atm

3. 2.36 atm

4. 4.361 atm

5. 4.0 atm

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Standard conditions (STP) is defined as

1. 273.15 K, 760 torr.

2. 0 K, 250 atm.

3. 100 K, 1 torr.

4. 273.15 K, 250 torr.

5. 0 K, 1 atm.

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A balloon filled with helium occupies 20.0 L at 1.50 atm and 25°C. How many moles of helium will there be in the balloon at STP?

A. 22.4 moles

B. 1.12 moles

C. 0.0446 moles

D. 0.893 moles

E. 1.23 moles

F. 4.55 moles

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What volume will 40.0 L of He at 50.00°C and 1201 torr occupy at STP?

A. 26.7 L

B. 18.6 L

C. 12.8 L

D. 53.4 L

E. 31.1 L

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What is the volume occupied at STP by a mixture of 4.00 g of He(g), 2.00 g of H2(g) and 32.0 g of O2(g)?

A. 6.15 L

B. 11.2 L

C. 22.4 L

D. 44.8 L

E. 67.2 L

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What volume will 3.12 grams of helium occupy at STP? 

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An ideal gas occupies 49.0 L at 994 torr and 41.0°C.

What volume would it occupy at STP? 

1. 0.0136 L

2. 73.7 L

3. 55.7 L 

4. 58.7 L

5. 105 L

6. 39.1 L

7. 69.9 L

8. 0.0179 L

9. 22.4 L

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If sufficient acid is used to react completely with 21.0 grams of Mg
Mg(s) + 2HCl(aq) → MgCl2(aq) + H2(g) 
what volume of hydrogen at STP would be produced?

1. 9.68 liters

2. 19.37 liters

3. 10.60 liters

4. 22.40 liters

5. 4.84 liters

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Lithium reacts with nitrogen gas according to the reaction: 

6 Li(s) + N2(g) → 2 Li3N(s)

What mass of lithium (in g) reacts completely with 58.5 mL of N2 gas at STP?

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Automobile air bags inflate following a serious impact. The impact triggers the chemical reaction: 

2 NaN3(s) →  2Na(s) + 3 N2(g)

If an automobile air bag has a volume of 11.8 L, what mass of NaN 3 (in g) is required to fully inflate the air bag upon impact? Assume STP conditions. 

 

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Use the molar volume of a gas at STP to determine the volume (in L) occupied by 33.6 g of neon at STP. 

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At STP what volume of N 2 will react completely with 22.2 L H 2 to produce NH3?

N2(g) + 3H2 (g) → 2NH 3 (g)

 

a. 7.4 L

b. 14.8 L

c. 22.2 L

d. 44.4 L

e. 66.6 L

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Which gas sample has the greatest volume at STP?

a. 5g Ar

b. 5g Rn

c. 5g Ne

d. 5g Kr

e. 5g Xe

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A sample of N2 gas occupies a volume of 746 mL at STP. What volume would N 2 gas occupy at 155°C at a pressure of 368 torr?

 

1. 983 mL

2. 566 mL

3. 3295 mL

4. 312 mL

5. 588 mL

6. 323 mL

7. 2415 mL

8. 1792 mL

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How many moles of O 2 (molar mass = 32.00 g/mol) are needed to react completely with 52.0 L of CH4(g) at STP to produce CO 2 and H2O? (molar mass (CH 4) = 16.04 g/mol)

a) 11.6

b) 2.32

c) 4.64

d) 52.0

e) 104

 

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Which of the following gases has the highest density at STP?

 

A. sulfur trioxide, SO 3

B. carbon dioxide

C. NO 2

D. argon

E. nitrogen 

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