Problem: Which substance has the lower boiling point? Explain.(b) NaBr or PBr3

FREE Expert Solution

We’re being asked to identify the compound with a lower boiling point among the given choices.


Recall that there are several types of intermolecular forces (IMF):

1. Ion-dipole interaction – occurs between an ion and a polar covalent compound; strongest IMF

2. Hydrogen bonding – occurs in compounds where hydrogen is directly connected to an electronegative element such as N, O, or F; 2nd strongest IMF

3. Dipole-dipole interaction – occurs between two polar covalent compounds; 3rd strongest IMF

4. Dispersion forces – occurs in all compounds and is the primary IMF exhibited by nonpolar compounds; weakest IMF


Compounds with lower intermolecular forces have lower boiling points. This is because they require less energy to be able to break the bonds during the phase transition.


So, we need to identify which among the given compounds has the weakest intermolecular forces.


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Problem Details

Which substance has the lower boiling point? Explain.

(b) NaBr or PBr3

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What scientific concept do you need to know in order to solve this problem?

Our tutors have indicated that to solve this problem you will need to apply the Intermolecular Forces and Physical Properties concept. If you need more Intermolecular Forces and Physical Properties practice, you can also practice Intermolecular Forces and Physical Properties practice problems.

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Based on our data, we think this problem is relevant for Professor Sanders' class at QC CUNY .

What textbook is this problem found in?

Our data indicates that this problem or a close variation was asked in Chemistry: The Molecular Nature of Matter and Change - Silberberg 8th Edition. You can also practice Chemistry: The Molecular Nature of Matter and Change - Silberberg 8th Edition practice problems.