Problem: Why is Avogadro’s number defined as 6.0221023 and not a simpler round number such as 1.001023?

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Avogadro’s number = 6.022 x 1023 entities

                                      entities = atoms, ions, molecules, particles, formula units

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Why is Avogadro’s number defined as 6.0221023 and not a simpler round number such as 1.001023?

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