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| Internal Energy | 22 mins | 0 completed | Learn |
| Calorimetry | 39 mins | 0 completed | Learn |
| Thermochemical Equation | 6 mins | 0 completed | Learn Summary |
| Hess's Law | 17 mins | 0 completed | Learn |
| Enthalpy of Formation | 13 mins | 0 completed | Learn Summary |
| End of Chapter 6 Problems | 52 mins | 0 completed | Learn |
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| Units of Energy |
| Endothermic & Exothermic Reactions |
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| Enthalpy |
Solution: Consider a balloon filled with helium at the following conditions.313 g He 1.00 atm 1910. L Molar Heat Capacity = 20.8 J/°C • molThe temperature of this balloon is decreased by 41.6°C as the volume de
Solution: Consider a balloon filled with helium at the following conditions.313 g He 1.00 atm 1910. L Molar Heat Capacity = 20.8 J/°C • molThe temperature of this balloon is decreased by 41.6°C as the volume de
Problem
Consider a balloon filled with helium at the following conditions.
313 g He
1.00 atm
1910. L
Molar Heat Capacity = 20.8 J/°C • mol
The temperature of this balloon is decreased by 41.6°C as the volume decreases to 1643 L, with the pressure remaining constant. Determine q, w, and ΔE (in kJ) for the compression of the balloon.
Solution
Recall: The change in internal energy (ΔE or ΔU) is given by:
The formula for work at constant pressure is:
where ΔV = change in volume (final V – initial V).
The formula for heat at constant pressure is:
where n = moles of compound, Cp = molar heat capacity at constant pressure, and ΔT = change in temperature (final T – initial T).
Practice Problems
Which statement is not correct?
a. Internal energ...
1 L.atm =101.325 J
When 2.00 kJ of energy is tran...
DO NOT FORGET TO WRITE A BALANCED CHEMICAL EQUATIO...
A system releases 415 kJ of heat and does 125 kJ o...
The gas in a piston is warmed and absorbs 655 J of...
The change in enthalpy (∆H) is a measure of the he...
What is internal energy?
Is internal energy a state function?
In which direction does energy flow?
What is heat?
Explain the difference between heat and temperatur...
How is the change in internal energy of a system r...
Explain how the sum of heat and work can be a stat...
What is pressure-volume work?
Identify each of the following energy exchanges as...
A gas-phase reaction was run in an apparatus desig...
Explain the significance of the law of conservatio...
Which of the following cannot leave or enter a clo...
What do we call the part of the universe that is n...
Which cannot leave or enter
an isolated system?
The accompanying photo shows a pipevine swallowtai...
The accompanying photo shows a pipevine swallowtai...
The accompanying photo shows a pipevine swallowtai...
Imagine a container placed in a tub of water, as d...
The accompanying photo shows a pipevine swallowtai...
You lose 9 pounds over a 26-day period. Which of t...
According to the first law of thermodynamics, what...
What is meant by the internal energy of a system?
By what means can the internal energy of a closed ...
Consider a system consisting of the following app...
Imagine that you are climbing a mountain.Is the di...
Imagine that you are climbing a mountain.Is the ch...
Consider a system consisting of the following app...
Consider the two diagrams below.
The equations y...
Consider the two diagrams below.
Would
similar r...
At 20 oC (approximately room temperature) the aver...
At 20 oC (approximately room temperature) the aver...
Suppose an Olympic diver who weighs
54.0
...
A sample of gas is contained in a cylinder-and-pis...
A sample of gas is contained in a cylinder-and-pis...
A sample of gas is contained in a cylinder-and-pis...
Consider the systems shown in the following figure...
A system goes from state 1 to state 2 and back to ...
In a thermodynamic study a scientist focuses on th...
A system goes from state 1 to state 2 and back to ...
In a thermodynamic study a scientist focuses on th...
A system goes from state 1 to state 2 and back to ...
A 200-lb man decides to add to his exercise routin...
Identify the force present, and explain whether wo...
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Identify the force present, and explain whether wo...
A standard air conditioner involves a refrigerant ...
Identify the force present, and explain whether wo...
A standard air conditioner involves a refrigerant ...
Identify the force present, and explain whether wo...
Is a human being an isolated, closed, or open syst...
Electrostatic potential energy. At finite sepa...
Write an equation that expresses the first law of ...
Under what conditions will the quantities q and w ...
The internal energy of an ideal gas depends only o...
What is meant by the term state function?
Give an example of a quantity that is a state func...
Is the volume of the system a state function?
H is a state function, but q is not a state functi...
A system that does work on its surroundings.If ...
You may want to reference (Pages 177 - 178) Sectio...
If a system does not change its volume during the ...
You may want to reference (Pages 177 - 178) Sectio...
Consider what happens when a sample of the explosi...
Consider what happens when a sample of the explosi...
What is work?
What is a state function?
List some examples of state functions.
Sign conventions for heat and work. Heat, q, ga...
Calculate E, if a system releases 66.6 kJ of heat...
Calculate E, if the system absorbs 7.26 kJ of hea...
A gas is confined to a cylinder under constant atm...
You may want to reference(Pages 166 - 172)Section ...
As shown here, one type of computer keyboard clea...
During a normal breath, our lungs expand about 0.5...
A 100-W lightbulb is placed in a cylinder equipped...
A sample of gas is contained in a cylinder-and-pis...
A gas is confined to a cylinder under constant atm...
Consider the accompanying energy diagram. (a) Does...
The contents of the closed box in each of the foll...
Which statement is true of the internal energy of ...
In the accompanying cylinder diagram a chemical pr...
Imagine a container placed in a tub of water, as d...
At constant pressure, which of these systems do wo...
Which statement is true of the internal energy of ...
Which one of the following statements is FALSE?The...
A rolling billiard ball collides with another bill...
Suppose an Olympic diver who weighs 52.0 kg execut...
All of the following statements are true EXCEPT:a....
(b) An adult person radiates heat to the surroundi...
Limestone stalactites and stalagmites are formed i...
A gas is allowed to expand at constant temperature...
For the following processes, calculate the change ...
For the following processes, calculate the change ...
For the following processes, calculate the change ...
A balloon is inflated from 0.0100 L to 0.400 L aga...
Which set of signs for q and w represent a system ...
A typical breath is around 0.5 L, but to get 2 sig...
A system that does no work but which receives heat...
Consider an ideal gas enclosed in a 1.00 L contain...
Consider an ideal gas enclosed in a 1.00 L contain...
The heat of vaporization of water at 373 K is 40.7...
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When 1 mol of a gas burns at constant pressure, it...
Which statement is true of a reaction in which ∆V ...
Which is true when a gas expands isothermically ag...
What is the change in the internal energy (in J) o...
If the volume of a system increases from 10.0 L to...
A certain liquid has Δvap Ho = 26.0 kJmol -1. Calc...
Which one of the following thermodynamic quantitie...
A gas at 25.00°C and 360.00 torr (760 torr = 1atm)...
Which set of signs for q and w represent a system ...
When fuel is burned in a cylinder equipped with a ...
Heat absorbed by a system at constant volume is eq...
Which of the following statements concerning the f...
Heat is1) A measure of temperature.2) A measure of...
A gas is allowed to expand, at a constant temperat...
Which of the following depicts a situation where t...
Calculate the amount of work done when 2.5 mole of...
Which statement is always true of the internal ene...
The internal energy of a system is the sum of all ...
Calculate the work for the expansion of CO2 from ...
Oxygen gas at 34.5°C is compressed from 45.7 L to ...
Which of the following is not a state function?A. ...
If the internal energy of the products of a reacti...
In which of these cases do the surroundings do wor...
Which of the following is true of the internal ene...
During an energy exchange, a chemical system absor...
Identify each of the following energy exchanges as...
A gas is confined to a cylinder fitted with a pist...
A gas is confined to a cylinder fitted with a pist...
A gas is confined to a cylinder fitted with a pist...
A gas is confined to a cylinder fitted with a pist...
The accompanying photo shows a pipevine swallowtai...
Consider the conversion of compound A into compoun...
Assume that the following reaction occurs at const...
Consider a system consisting of the following appa...
In the cylinder diagrammed below , a chemical proc...
In the cylinder diagrammed below , a chemical proc...
A balloonist begins a trip in a helium-filled ball...
Suppose an Olympic diver who weighs 54.0 kg execut...
Suppose an Olympic diver who weighs 54.0 kg execut...
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An aluminum can of a soft drink is placed in a fre...
Energy diagram for the reaction 2 H2(g) + O2(g) → ...
Consider the systems shown in the following figure...
The circles represent a phase change at constant t...
The circles represent a phase change at constant t...
The circles represent a phase change at constant t...
The scene below represents a physical change takin...
The scene below represents a physical change takin...
The scene below represents a physical change takin...
In which of the following systems is(are) work don...
Consider the energy diagram shown in the figure .D...
Consider the energy diagram shown in the figure .W...
You may want to reference (Pages 167 - 172) Sectio...
The contents of the closed box in each of the illu...
Consider a system consisting of two oppositely cha...
Consider a system consisting of two oppositely cha...
Which of the following is true of the internal ene...
Consider a system consisting of two oppositely cha...
The internal energy of an ideal gas depends only o...
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You may have noticed that when you compress the ai...
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Which of the following is true of a reaction in wh...
The diagram shows four states of a system, each wi...
The diagram shows four states of a system, each wi...
The diagram shows four states of a system, each wi...
Why is the change in enthalpy usually easier to me...
What is the value of ΔEDelta E if Efinal equals Ei...
Three gas-phase reactions were run in a constant-p...
You may want to reference (Pages 177 - 178) Sectio...
Three gas-phase reactions were run in a constant-p...
Three gas-phase reactions were run in a constant-p...
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Identify each energy exchange as primarily heat or...
Nitrogen gas reacts with hydrogen gas to form ammo...
Determine whether the sign of E is positive or neg...
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Identify each energy exchange as heat or work and ...
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Suppose that the gas-phase reaction 2NO(g) + O2(g)...
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When 1 mol of a fuel is burned at constant pressur...
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Limestone stalactites and stalagmites are formed i...
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A 21.0-L volume of an ideal gas in a cylinder with...
Calculate E, if q = 0.766 kJ and w = -840 J .
When 1 mol of a gas burns at constant pressure, it...
When 1 mol of a gas burns at constant pressure, it...
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You may want to reference (Pages 172 - 176)Section...
Isooctane (C8H18; d = 0.692 g/mL) is used as the f...
You may want to reference (Pages 172 - 176)Section...
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A gas is compressed from an initial volume of 5.60...
Consider the following cyclic process carried out ...
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A sample of an ideal gas at 15.0 atm and 10.0 L is...
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A piston performs work of 210. L ? atm on the surr...
Consider a mixture of air and gasoline vapor in a ...
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One mole of nitrogen gas confined within a cylinde...
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A 21.0-L volume of an ideal gas in a cylinder with...
An amount of an ideal gas expands from 12.1 L to 2...
When 1 mol of a gas burns at constant pressure, it...
When 1 mol of a gas burns at constant pressure, it...
A cylinder with a moving piston expands from an in...
Internal energy is a state function, but heat and ...
Isooctane (C8H18; d = 0.692 g/mL) is used as the f...
Consider the following changes: b. CO (g) + H2O (g...
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One mole of an ideal gas is expanded from a volume...
Automobile airbags contain solid sodium azide, NaN...
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