Ch.11 - Liquids, Solids & Intermolecular ForcesWorksheetSee all chapters
All Chapters
Ch.1 - Intro to General Chemistry
Ch.2 - Atoms & Elements
Ch.3 - Chemical Reactions
BONUS: Lab Techniques and Procedures
BONUS: Mathematical Operations and Functions
Ch.4 - Chemical Quantities & Aqueous Reactions
Ch.5 - Gases
Ch.6 - Thermochemistry
Ch.7 - Quantum Mechanics
Ch.8 - Periodic Properties of the Elements
Ch.9 - Bonding & Molecular Structure
Ch.10 - Molecular Shapes & Valence Bond Theory
Ch.11 - Liquids, Solids & Intermolecular Forces
Ch.12 - Solutions
Ch.13 - Chemical Kinetics
Ch.14 - Chemical Equilibrium
Ch.15 - Acid and Base Equilibrium
Ch.16 - Aqueous Equilibrium
Ch. 17 - Chemical Thermodynamics
Ch.18 - Electrochemistry
Ch.19 - Nuclear Chemistry
Ch.20 - Organic Chemistry
Ch.22 - Chemistry of the Nonmetals
Ch.23 - Transition Metals and Coordination Compounds

Solution: Four alcohols have the formula C4H9OH:1-butanol, 2-butanol (or sec-butanol), isobutanol (or 2-methyl-1-propanol), and tert-butanol (or 2-methy;-2-propanol).They are examples of isomers, or compounds t

Problem

Four alcohols have the formula C4H9OH:

1-butanol, 2-butanol (or sec-butanol), isobutanol (or 2-methyl-1-propanol), and tert-butanol (or 2-methy;-2-propanol).

They are examples of isomers, or compounds that have the same molecular formula but different molecular structures. The below table gives data on the isomers:

Using the Clausius-Clapeyron equation, rank the isomers of butanol in order of decreasing vapor pressure at 25 °C. Does the ranking agree with any conventional wisdom based on the ΔvapH Values or the normal boiling points?