# Problem: 1. In which of the following is it necessary to use an expanded octet to represent a Lewis structure that has zero formal charges on the central atom? A) SiCl2F2 ; B) SO4 2− ; C) CO32− ; D) PO43− ; E) SO3 A. D and E only B. A and B only C. E only D. C, D, and E only E. B, D, and E only

###### FREE Expert Solution

We’re being asked to identify the compound that it is necessary to use an expanded octet to represent a Lewis structure that has zero formal charges on the central atom

Recall that the octet rule states that an element is surrounded by eight electrons in the Lewis structure.

Exceptions to this rule occur when:

• there is an odd number of electrons, like in radicals

• there are less than 8 electrons or incomplete octet

• there are more than 8 electrons or expanded octet. This occurs to nonmetals from Period 3 to 7.

For this problem, we need to draw the Lewis structure for each compound.

To do so, we need the following steps:

Step 1: Determine the central atom in this molecule.

Step 2: Calculate the total number of valence electrons present.

Step 3: Draw the Lewis structure for the molecule.

97% (151 ratings) ###### Problem Details

1. In which of the following is it necessary to use an expanded octet to represent a Lewis structure that has zero formal charges on the central atom?

A) SiCl2F2

B) SO4 2−

C) CO32−

D) PO43−

E) SO

A. D and E only

B. A and B only

C. E only

D. C, D, and E only

E. B, D, and E only

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Our tutors have indicated that to solve this problem you will need to apply the Lewis Dot Structures: Exceptions concept. You can view video lessons to learn Lewis Dot Structures: Exceptions. Or if you need more Lewis Dot Structures: Exceptions practice, you can also practice Lewis Dot Structures: Exceptions practice problems.