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Problem: Lanthanum metal forms cations with a charge of 3+. Consider the following observations about the chemistry of lanthanum: When lanthanum metal is exposed to air, a white solid (compound A) is formed that contains lanthanum and one other element. When lanthanum metal is added to water, gas bubbles are observed and a different white solid (compound B) is formed. Both A and B dissolve in hydrochloric acid to give a clear solution. When either of these solutions is evaporated, a soluble white solid (compound C) remains. If compound C is dissolved in water and sulfuric acid is added, a white precipitate (compound D) forms.Propose identities for the substances A, B, C, and D.

FREE Expert Solution

compound A: lanthanum metal is exposed to air

4 La (s) + 3 O2 (g) → 2 La2O3 (s)


compound B: lanthanum metal is added to water

2 La (s) + 6 H2O (l) → 2 La(OH)3 (s) + 3 H(g)


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Problem Details

Lanthanum metal forms cations with a charge of 3+. Consider the following observations about the chemistry of lanthanum: When lanthanum metal is exposed to air, a white solid (compound A) is formed that contains lanthanum and one other element. When lanthanum metal is added to water, gas bubbles are observed and a different white solid (compound B) is formed. Both A and B dissolve in hydrochloric acid to give a clear solution. When either of these solutions is evaporated, a soluble white solid (compound C) remains. If compound C is dissolved in water and sulfuric acid is added, a white precipitate (compound D) forms.


Propose identities for the substances A, B, C, and D.

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