Solubility Rules:
•Soluble Ionic Compounds:
▪ Group 1A ions (Li+, Na+, K+, etc.) and Ammonium ion (NH4+) are soluble
▪ Nitrates (NO3-), Acetates (CH3COO- or C2H3O2-), and most Perchlorates (ClO4-) are soluble
▪ Cl-, Br-, and I- are soluble except when paired with Ag+, Pb2+, Cu+, Hg22+
▪ Sulfates (SO42-) are soluble except those of Ca2+, Sr2+, Ba2+, Ag+, and Pb2+
• Insoluble Ionic Compounds:
A student was given a solid containing a mixture of nitrate salts. The sample completely dissolved in water, and upon addition of dilute HCl, no precipitate formed. The pH was lowered to about 1 and H2S was bubbled through the solution. No precipitate formed. The pH was adjusted to 8 and H2S was again bubbled in. This time, a precipitate formed.
Which compounds might have been present in the unknown?
a) Ca(NO3)2
b) AgNO3
c) Fe(NO)3
d) Cr(NO3)3
e) Cu(NO3)2
f) Bi(NO3)2
g) Co(NO3)2
h) KNO3
Frequently Asked Questions
What scientific concept do you need to know in order to solve this problem?
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