Ch. 17 - Chemical ThermodynamicsWorksheetSee all chapters
All Chapters
Ch.1 - Intro to General Chemistry
Ch.2 - Atoms & Elements
Ch.3 - Chemical Reactions
BONUS: Lab Techniques and Procedures
BONUS: Mathematical Operations and Functions
Ch.4 - Chemical Quantities & Aqueous Reactions
Ch.5 - Gases
Ch.6 - Thermochemistry
Ch.7 - Quantum Mechanics
Ch.8 - Periodic Properties of the Elements
Ch.9 - Bonding & Molecular Structure
Ch.10 - Molecular Shapes & Valence Bond Theory
Ch.11 - Liquids, Solids & Intermolecular Forces
Ch.12 - Solutions
Ch.13 - Chemical Kinetics
Ch.14 - Chemical Equilibrium
Ch.15 - Acid and Base Equilibrium
Ch.16 - Aqueous Equilibrium
Ch. 17 - Chemical Thermodynamics
Ch.18 - Electrochemistry
Ch.19 - Nuclear Chemistry
Ch.20 - Organic Chemistry
Ch.22 - Chemistry of the Nonmetals
Ch.23 - Transition Metals and Coordination Compounds

Solution: Consider the following reaction:H2O(g) + Cl 2O(g) → 2HOCl(g)     K 298 = 0.090For Cl2O(g),       ΔG°f = 97.9 kJ/mol       ΔH°f = 80.3 kJ/mol           S° = 266.1 J/K • mold. Estimate ΔH°f and S° for HOCl(g).

Problem

Consider the following reaction:

H2O(g) + Cl 2O(g) → 2HOCl(g)     K 298 = 0.090

For Cl2O(g),
       ΔG°f = 97.9 kJ/mol
       ΔH°f = 80.3 kJ/mol
           S° = 266.1 J/K • mol

d. Estimate ΔH°f and S° for HOCl(g).