Ch.18 - ElectrochemistryWorksheetSee all chapters
All Chapters
Ch.1 - Intro to General Chemistry
Ch.2 - Atoms & Elements
Ch.3 - Chemical Reactions
BONUS: Lab Techniques and Procedures
BONUS: Mathematical Operations and Functions
Ch.4 - Chemical Quantities & Aqueous Reactions
Ch.5 - Gases
Ch.6 - Thermochemistry
Ch.7 - Quantum Mechanics
Ch.8 - Periodic Properties of the Elements
Ch.9 - Bonding & Molecular Structure
Ch.10 - Molecular Shapes & Valence Bond Theory
Ch.11 - Liquids, Solids & Intermolecular Forces
Ch.12 - Solutions
Ch.13 - Chemical Kinetics
Ch.14 - Chemical Equilibrium
Ch.15 - Acid and Base Equilibrium
Ch.16 - Aqueous Equilibrium
Ch. 17 - Chemical Thermodynamics
Ch.18 - Electrochemistry
Ch.19 - Nuclear Chemistry
Ch.20 - Organic Chemistry
Ch.22 - Chemistry of the Nonmetals
Ch.23 - Transition Metals and Coordination Compounds

Solution: In basic solution, Se2− and SO32− ions react spontaneously:2Se2−(aq) + 2SO32−(aq) + 3H2O(l) ⟶ 2Se(s) + 6OH−(aq) + S2O32−(aq)       E°cell = 0.35 V(b) If E°sulfite is −0.57 V, calculate E°selenium.

Problem

In basic solution, Se2− and SO32− ions react spontaneously:

2Se2−(aq) + 2SO32−(aq) + 3H2O(l) ⟶ 2Se(s) + 6OH(aq) + S2O32−(aq)       E°cell = 0.35 V

(b) If E°sulfite is −0.57 V, calculate E°selenium.