Problem: The highest occupied molecular orbital of a molecule is abbreviated as the HOMO. The lowest unoccupied molecular orbital in a molecule is called the LUMO. Experimentally, one can measure the difference in energy between the HOMO and LUMO by taking the electronic absorption (UV-visible) spectrum of the molecule. Peaks in the electronic absorption spectrum can be labeled as π2p–π2p*, σ2s–σ2s*, and so on, corresponding to electrons being promoted from one orbital to another. The HOMO-LUMO transition corresponds to molecules going from their ground state to their first excited state.The electronic absorption spectrum of the N2 molecule has the lowest energy peak at 170 nm. To what orbital transition does this correspond?

FREE Expert Solution

The ground-state electron configuration of nitrogen is: 

N: 1s22s22p3

This corresponds to a valence electron configuration:

2s22p3

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Problem Details

The highest occupied molecular orbital of a molecule is abbreviated as the HOMO. The lowest unoccupied molecular orbital in a molecule is called the LUMO. Experimentally, one can measure the difference in energy between the HOMO and LUMO by taking the electronic absorption (UV-visible) spectrum of the molecule. Peaks in the electronic absorption spectrum can be labeled as π2p–π2p*, σ2s–σ2s*, and so on, corresponding to electrons being promoted from one orbital to another. The HOMO-LUMO transition corresponds to molecules going from their ground state to their first excited state.

The electronic absorption spectrum of the N2 molecule has the lowest energy peak at 170 nm. To what orbital transition does this correspond?

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