Ch.8 - Periodic Properties of the ElementsWorksheetSee all chapters
All Chapters
Ch.1 - Intro to General Chemistry
Ch.2 - Atoms & Elements
Ch.3 - Chemical Reactions
BONUS: Lab Techniques and Procedures
BONUS: Mathematical Operations and Functions
Ch.4 - Chemical Quantities & Aqueous Reactions
Ch.5 - Gases
Ch.6 - Thermochemistry
Ch.7 - Quantum Mechanics
Ch.8 - Periodic Properties of the Elements
Ch.9 - Bonding & Molecular Structure
Ch.10 - Molecular Shapes & Valence Bond Theory
Ch.11 - Liquids, Solids & Intermolecular Forces
Ch.12 - Solutions
Ch.13 - Chemical Kinetics
Ch.14 - Chemical Equilibrium
Ch.15 - Acid and Base Equilibrium
Ch.16 - Aqueous Equilibrium
Ch. 17 - Chemical Thermodynamics
Ch.18 - Electrochemistry
Ch.19 - Nuclear Chemistry
Ch.20 - Organic Chemistry
Ch.22 - Chemistry of the Nonmetals
Ch.23 - Transition Metals and Coordination Compounds

Solution: Detailed calculations show that the value of Zeff for the outermost electrons in Na and K atoms is 2.51+ and 3.49+, respectively.What value do you estimate for Zeff experienced by the outermost electron in both Na and K by assuming core electrons contribute 1.00 and valence electrons contribute 0.00 to the screening constant? What values do you estimate for Zeff using Slater’s rules?Which approach gives a more accurate estimate of Zeff?

Problem

Detailed calculations show that the value of Zeff for the outermost electrons in Na and K atoms is 2.51+ and 3.49+, respectively.

What value do you estimate for Zeff experienced by the outermost electron in both Na and K by assuming core electrons contribute 1.00 and valence electrons contribute 0.00 to the screening constant? What values do you estimate for Zeff using Slater’s rules?

Which approach gives a more accurate estimate of Zeff?