Ch.13 - Chemical KineticsWorksheetSee all chapters
All Chapters
Ch.1 - Intro to General Chemistry
Ch.2 - Atoms & Elements
Ch.3 - Chemical Reactions
BONUS: Lab Techniques and Procedures
BONUS: Mathematical Operations and Functions
Ch.4 - Chemical Quantities & Aqueous Reactions
Ch.5 - Gases
Ch.6 - Thermochemistry
Ch.7 - Quantum Mechanics
Ch.8 - Periodic Properties of the Elements
Ch.9 - Bonding & Molecular Structure
Ch.10 - Molecular Shapes & Valence Bond Theory
Ch.11 - Liquids, Solids & Intermolecular Forces
Ch.12 - Solutions
Ch.13 - Chemical Kinetics
Ch.14 - Chemical Equilibrium
Ch.15 - Acid and Base Equilibrium
Ch.16 - Aqueous Equilibrium
Ch. 17 - Chemical Thermodynamics
Ch.18 - Electrochemistry
Ch.19 - Nuclear Chemistry
Ch.20 - Organic Chemistry
Ch.22 - Chemistry of the Nonmetals
Ch.23 - Transition Metals and Coordination Compounds

Solution: In a study of nitrosyl halides, a chemist proposes the following mechanism for the synthesis of nitrosyl bromide:NO(g) + Br2(g) ⇌ NOBr2(g)               [fast]NOBr2(g) + NO(g) ⟶ 2NOBr(g)        [slow]

Problem

In a study of nitrosyl halides, a chemist proposes the following mechanism for the synthesis of nitrosyl bromide:

NO(g) + Br2(g) ⇌ NOBr2(g)               [fast]
NOBr2(g) + NO(g) ⟶ 2NOBr(g)        [slow]

If the rate law is rate = k[NO]2[Br2], is the proposed mechanism valid? If so, show that it satisfies the three criteria for validity.