Problem: The reaction of CO with Cl2 gives phosgene (COCl2), a nerve gas that was used in World War I. Use the mechanism shown here to complete the following exercises:Cl2 (g) ⇌ 2 Cl (g) (fast, k1 represents the forward rate constant, k−1 the reverse rate constant)CO(g) + Cl(g) ⟶ COCl(g) (slow, k2 the rate constant)COCl(g) + Cl(g) ⟶ COCl2 (g) (fast, k3 the rate constant)(c) Write the rate law for each elementary reaction.

🤓 Based on our data, we think this question is relevant for Professor Barrows' class at GVSU.

FREE Expert Solution

Write the rate law for each elementary reaction.

Step 1: Cl2(g) 2 Cl (g) (fast, krepresents the forward rate constant, k−1 the reverse rate constant)
Step 2: CO
(g) + Cl(g) COCl(g) (slow, k2 the rate constant)
Step 3: COCl
(g) + Cl(g) COCl2(g) (fast, k3 the rate constant)


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Problem Details

The reaction of CO with Cl2 gives phosgene (COCl2), a nerve gas that was used in World War I. Use the mechanism shown here to complete the following exercises:

Cl2 (g) ⇌ 2 Cl (g) (fast, krepresents the forward rate constant, k−1 the reverse rate constant)
CO(g) + Cl(g) ⟶ COCl(g) (slow, k2 the rate constant)
COCl(g) + Cl(g) ⟶ COCl2 (g) (fast, k3 the rate constant)

(c) Write the rate law for each elementary reaction.

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What scientific concept do you need to know in order to solve this problem?

Our tutors have indicated that to solve this problem you will need to apply the Reaction Mechanism concept. If you need more Reaction Mechanism practice, you can also practice Reaction Mechanism practice problems.

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Based on our data, we think this problem is relevant for Professor Barrows' class at GVSU.

What textbook is this problem found in?

Our data indicates that this problem or a close variation was asked in Chemistry - OpenStax 2015th Edition. You can also practice Chemistry - OpenStax 2015th Edition practice problems.