Recall that ** Graham's Law of Effusion** allows us to compare the rate of effusion of two gases. Graham's Law states that the rate of effusion of a gas is inversely proportional to its molar mass.

$\mathbf{rate}\mathbf{=}\frac{\mathbf{1}}{\sqrt{{\mathbf{MM}}_{\mathbf{gas}}}}$

This means that when comparing two gases:

$\overline{)\frac{{\mathbf{rate}}_{\mathbf{gas}\mathbf{}\mathbf{1}}}{{\mathbf{rate}}_{\mathbf{gas}\mathbf{}\mathbf{2}}}{\mathbf{=}}\sqrt{\frac{{\mathbf{MM}}_{\mathbf{gas}\mathbf{}\mathbf{2}}}{{\mathbf{MM}}_{\mathbf{gas}\mathbf{}\mathbf{1}}}}}$

Suppose you have two 1-L flasks, one containing N_{2} at STP and the other containing CH_{4} at STP.

You may want to reference (Pages 415 - 419)Section 10.8 while completing this problem.

How do these systems compare with respect to the rate of effusion through a pinhole leak?

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