Ch.12 - SolutionsWorksheetSee all chapters
All Chapters
Ch.1 - Intro to General Chemistry
Ch.2 - Atoms & Elements
Ch.3 - Chemical Reactions
BONUS: Lab Techniques and Procedures
BONUS: Mathematical Operations and Functions
Ch.4 - Chemical Quantities & Aqueous Reactions
Ch.5 - Gases
Ch.6 - Thermochemistry
Ch.7 - Quantum Mechanics
Ch.8 - Periodic Properties of the Elements
Ch.9 - Bonding & Molecular Structure
Ch.10 - Molecular Shapes & Valence Bond Theory
Ch.11 - Liquids, Solids & Intermolecular Forces
Ch.12 - Solutions
Ch.13 - Chemical Kinetics
Ch.14 - Chemical Equilibrium
Ch.15 - Acid and Base Equilibrium
Ch.16 - Aqueous Equilibrium
Ch. 17 - Chemical Thermodynamics
Ch.18 - Electrochemistry
Ch.19 - Nuclear Chemistry
Ch.20 - Organic Chemistry
Ch.22 - Chemistry of the Nonmetals
Ch.23 - Transition Metals and Coordination Compounds

According to Henry's Law, at a constant temperature the amount of a gas dissolved in a solvent is directly proportional to its partial pressure when it is in equilibrium with its liquid phase. 

Solutions & Solubility 

When an ionic solid dissolves, ions leave the solid and become dispersed in the solvent. This solution can be classified as saturatedunsaturated or supersaturated

Concept #1: Saturated, Unsaturated and Supersaturated Solutions. 


Welcome back, guys! In this new video, we're going to take a closer look at solubility. What we should realize is that solubility can have two other names associated with it. Solubility is also called concentration. If they say concentration, it's the same thing as solubility. Another name for concentration or solubility would be molarity. Molarity is moles of solute per liter of solution. Solubility is how much solute can we dissolve in our solvent. They're both basically saying the same exact thing.
When we dissolve a solid, what's going to happen is ions are going to leave that solid and basically dissolve within the solvent. What we should realize is that there’s basically a threshold, a limit to how much solute we can dissolve into something. After a certain point, we can try and try and try and add more and more solid but none of it is going to dissolve because the water, the liquid, has reached its maximum amount of dissolving.
We should realize that when it comes to this, there are different terms we need to be familiar with. We're going to say in a blank solution, the maximum amount of dissolved solute is present in the solvent. What I mean by this is let's say we have a bucket of water. Let’s say that this bucket of water can only dissolve up to 100 grams of solute. Let's say I take 102 grams of solute and I dump it into that bucket. The bucket will dissolve the hundred grams, no problem. But those extra two grams I have are not going to dissolve. They're going to remain as solids clumped up at the bottom of the bucket of water. We're going to say this solution has reached its maximum amount of solute. We're going to say that this solution is saturated. Remember, saturated means that the solution, the solvent, has reached its maximum amount in grams, in moles, whatever of the amount of solute it can dissolve successfully.
In a blank solution, additional amounts of solute can be further dissolved in the solvent. We have our same bucket of water. We say that it can dissolve 100 grams. But let's say I take 90 grams of solute and I dump it in there. All 90 grams will completely dissolve and we still have room to dissolve 10 more grams. We're going to say that this solution is unsaturated. It still has room for it to dissolve more solvent. It will successfully dissolve the 90 but we still have room for 10 more.
Finally, our last type we're going to say in this, in a blank solution more than the equilibrium concentration of solute has been dissolved. What this means is again I have my bucket of water and somehow I get this bucket even though it's supposed to only dissolve 100, I get it to dissolve those extra 2 grams I talked about earlier. We're going to say that this solution is supersaturated. It's gone beyond its limit. You might ask, how do we accomplish this? What you’re going to say here is to do this, you’d have to apply heat. Heat is needed to do this. If you supply heat to it, you'll be able to dissolve beyond your maximum.
But here's the thing. Supersaturated solutions are very unstable. The moment that I take away the heat from the solution, the extra 2 that I dissolved is going to re-solidify and form a precipitate or what we call a solid on the bottom. Remember, heat causes us to create a supersaturated solution. I can dissolve 102 grams, all 102 of it dissolves completely. Once I take away my heat, the extra 2 grams that I have here are going to form a precipitate. They're going to what we say recrystallize. They’re going to recrystallize at the bottom of my bucket of water.
Saturated, unsaturated, supersaturated – all of them deal with solubility, how much solute can I dissolve. All of them deal with molarity. Remember, solubility, concentration, molarity – all the same thing.

In a hypothetical solution 100 mL of water can dissolve up to 100 g of solute. In a SATURATED solution the water has reached its maximum amount of dissolve solute. 

In an UNSATURATED solution additional amounts of solute can be further dissolved in the solvent. 

In a SUPERSATURATED solution the solvent has dissolved beyond its maximum solubility. 

Example #1: Caffeine is about 10 times as soluble in warm water as in cold water. A student puts a hot-water extract caffeine into an ice bath, and some caffeine crystallizes. What is the identity of the solution before it’s been placed in an ice bath?

a) Saturated

b) Supersaturated

c) Unsaturated

d) Not enough information to answer the question. 

Concept #2: Understanding Henry's Law


Connected to this is what we call Henry's law. Basically, Henry's law talks about how much gas can we get to dissolve in a solvent. Henry’s law explains the relationship between gas, pressure, and solubility. The solubility of a gas, and remember solubility just means molarity, is directly proportional to the partial pressure of the gas above the solution. All this means is if I increase my pressure, then I increase the solubility of my gas. Because you have to think about in this way. We have a couple of water or something, a bucket of water and we have gas particles above it, floating on top of it.
Here, this represents my pressure. If I push down on this piston, it’s going to push down against the gas. The gases have only one place to go. The gases will go into the liquid. The gas is dissolved in the liquid. That's what we mean by Henry's law. Basically if I increase my pressure, I increase how much gas I have in my solvent because they have no other place to go from pushing down on them.
We're going to say again, solubility of the gas means molarity of the gas. P here, P of the gas means the partial pressure of that gas. Partial pressure of that gas just means that’s the pressure of only that gas. In a container, we usually don't have one type of gas. We usually have a mixture of gases. Collectively, that is the total pressure. But each type with gas has its own individual pressure. That individual pressure is called partial pressure.
Then we're going to say kH here is known as Henry's constant. Together, all three of these give us Henry's law. Remember what solubility is and remember, increasing the pressure will increase the solubility of a gas. 

Henry's Law relates the solubility of a gas over a solution based on the factors of temperature, volume and pressure. 

Example #2: Henry’s Law Constant for nitrogen in water is 1.67 x 10-4 M•atm-1. If a closed canister contains 113 ppb nitrogen, what would be its pressure in atm? 

As the temperature of the solution increases more and more gas molecules will exit the solvent. 

Practice: In general, as the temperature increases, the solubility of gas in a given liquid ________________, and the solubility of most solids in a given liquid ________________. 

a. Increases, increases

b. increases, decreases

c. decreases, increases

d. decreases, decreases

Practice: At a partial pressure of acetylene 1.35 atm, 1.21 moles of it dissolves in 1.05 L of acetonitrile. If the partial pressure of acetylene in acetone is increased to 12.0 atm, then what is its solubility?