Clutch Prep is now a part of Pearson
Ch.9 - Polyprotic Acid-Base EquilibriaWorksheetSee all chapters
All Chapters
Ch.1 - Chemical Measurements
Ch.2 - Tools of the Trade
Ch.3 - Experimental Error
Ch.4 + 5 - Statistics, Quality Assurance and Calibration Methods
Ch.6 - Chemical Equilibrium
Ch.7 - Activity and the Systematic Treatment of Equilibrium
Ch.8 - Monoprotic Acid-Base Equilibria
Ch.9 - Polyprotic Acid-Base Equilibria
Ch.10 - Acid-Base Titrations
Ch.11 - EDTA Titrations
Ch.12 - Advanced Topics in Equilibrium
Ch.13 - Fundamentals of Electrochemistry
Ch.14 - Electrodes and Potentiometry
Ch.15 - Redox Titrations
Ch.16 - Electroanalytical Techniques
Ch.17 - Fundamentals of Spectrophotometry
BONUS: Chemical Kinetics
Sections
Diprotic Acids and Bases
Polyprotic Acids and Bases
Diprotic Buffers
Polyprotic Buffers
Principal Species
Isoelectric and Isoionic pH

Depending on the pH of the solution different forms of protic product can exist. 

Principal Species

Concept #1: By comparing the pH to the pKa value you can determine which form will predominate within a given solution. 

Expert Q&A

Ask unlimited questions and get expert help right away.

Example #1: What is the predominant form of the diprotic acid, methionine, at a pH equal to 4.18? Ka1 = 6.6 x 10-3 and Ka2 = 8.3 x 10-10.

Expert Q&A

Ask unlimited questions and get expert help right away.

Example #2: What is the predominant form of histidine at a pH equal to 8.00? pKa1 = 1.6, pKa2 = 5.97 and pKa3 = 9.28. 

Expert Q&A

Ask unlimited questions and get expert help right away.

Example #3: What is the second most predominant form in the previous question?

Expert Q&A

Ask unlimited questions and get expert help right away.

Expert Q&A

Ask unlimited questions and get expert help right away.